Laboratory of Macromolecular and Organic Materials – LMOM

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Prof. Holger Frauenrath

Peer Reviewed Articles

  • 76129 X. Li, P.J. Wolanin, L.R. MacFarlane, R.L. Harniman, J. Qian, O.E.C. Gould, T.G. Dane, J. Rudin, M.J. Cryan, T. Schmaltz, H. Frauenrath, M.A. Winnik, C.F.J. Faul, I. Manners, Uniform electroactive fibre-like micelle nanowires for organic electronics, Nature Communications, 2017, 8, 15909,.
    • 75127 J. Cretenoud, B. Özen, T. Schmaltz, D. Görl, A. Fabrizio, C. Corminboeuf, F. Fadaei, R. Scopelliti, H. Frauenrath, Synthesis and Characterisation of Semiaromatic Polyamides Comprising Benzofurobenzofuran Repeating Units , Polymer Chemistry, 2017, 0, DOI: 10.1039/C7PY00129K,.
      • 74125 T. Schmaltz, G. Sforazzini, T. Reichert, H. Frauenrath, Self-Assembled Monolayers as Patterning Tool for Organic Electronic Devices, Advanced Materials, 2017, 0, DOI: 10.1002/adma.201605286,.
        • 73126 J. Cretenoud, S. Galland, C.J.G. Plummer, V. Michaud, A. Bayer, N. Lamberts, B. Hoffmann, H. Frauenrath, High-temperature copolyamides obtained by the efficient transamidation of crystalline–crystalline polyamide blends, Journal of Applied Polymer Science, 2017, 134, 44349,.
          • 72121 S. Schrettl, B. Schulte, H. Frauenrath, Templating for Hierarchical Structure Control in Carbon Materials., Nanoscale, 2016, 8, 18828-18848,.
            • 71120 S. Schrettl, B. Schulte, C. Stefaniu, J. Oliveira, G. Brezesinski, H. Frauenrath, Preparation of Carbon Nanosheets at Room Temperature , JoVE (Journal of Visualized Experiments), 2016, 0, e53505,.
              • 7061 J. Gebers, D. Rolland, R. Marty, S. Suarez, L. Cervini, R. Scopelliti, J.C. Brauer, H. Frauenrath, Solubility and Crystallizability: Facile Access to Functionalized π-Conjugated Compounds with Chlorendylimide Protecting Groups, Chem. Eur. J., 2015, 21, 1542-1553,.
                • 6956 S. Schrettl, E. Contal, T. Hoheisel, M. Fritzsche, S. Balog, R. Szilluweit, H. Frauenrath, Facile synthesis of oligoyne amphiphiles and their rotaxanes, Chem. Sci., 2015, 6, 564–574,.
                  • 6859 G. Rinke, S. Rauschenbach, S. Schrettl, T.N. Hoeheisel, J. Bloheisel, J. Blohm, R. Gutzler, F. Rosei, H. Frauenrath, K. Kern, Soft-Landing Electrospray Ion Beam Deposition of Sensitive Oligoynes on Surfaces in Vacuum, Int. J. Mass. Spectrometry, 2015, 377, 228-234.
                    • 6757 R. Marty, R.Nignon, D. Leite, H. Frauenrath, Two-Fold Odd-Even Effect in Self-Assembled Nanowires from Oligopeptide-Polymer-Substitued Perylene Bisimides, J. Am. Chem. Soc., 2014, 136, 3919-3927.
                      • 661 S. Schrettl, C. Stefaniu, C. Schwieger, G. Pasche, E. Oveisi, Y. Fontana, A. Fontcuberta i Morral, J. Reguera, R. Petraglia, C. Corminboeuf, G. Brezesinski, H. Frauenrath, Functional Carbon Nanosheets Prepared from Hexayne Amphiphile Monolayers at Room Temperature, Nature Chem., 2014, 6, 468-476,.
                      • 6553 E. Croisier, S. Liang, T. Schweizer, S. Balog, M. Mionic, R. Snellings, J. Cugnoni, V. Michaud, H. Frauenrath, A Toolbox of Oligopeptide-Modified Polymers for Tailored Elastomers, Nature Commun., 2014, 5, 4278.
                        • 6458 R. Marty, H. Frauenrath, J. Helbing, Aggregates from Perylene Bisimide Oligopeptides as a Test Case for Giant Vibrational Circular Dichroism, J. Phys. Chem. B, 2014, 118, 11152-11160.
                          • 6354 T. N. Hoheisel, S. Schrettl, R. Marty, T. K. Todorova, C. Corminboeuf, A. Sienkiewicz, R. Scopelliti, W. B. Schweizer, H. Frauenrath, A Multistep Single-Crystal-to-Single-Crystal Bromodiacetylene Dimerization, Nature Chem., 2013, 5, 327–334.
                            • highlighted in Chimia, 2013, 67 (5), 349.
                          • 6255 R. Marty, R. Szilluweit, A. Sanchez–Ferrer, S. Bolisetty, J. Adamcik, R. Mezzenga, E. C. Spitzner, M. Feifer, S. N. Steinmann, C. Corminboeuf, H. Frauenrath, Hierarchically Structured Microfibers of ‘Single Stack’ Perylene Bisimide and Quaterthiophene Nanowires, ACS Nano, 2013, 7, 8498–8508.
                            • 6162 T.M. Hermans, H. Frauenrath, F. Stellacci, Droplets Out of Equilibrium, Science, 2013, 341, 243-244.
                              • 6063 L. F. Tian, E. Croisier, H. Frauenrath, Materials Taking a Lesson From Nature, Chimea, 2013, 67, 782-787.
                                • 5913 R. Szilluweit, T. N. Hoheisel, M. Fritzsche, B. Ketterer, A. Fontcuberta i Morral, D. Demurtas, V. Laporte, R. Verel, S. Bolisetty, R. Mezzenga, H. Frauenrath, Low-Temperature Preparation of Tailored Carbon Nanostructures in Water, Nano Lett., 2012, 12, 2573-2578.
                                  • highlighted in MRS Bulletin, 2012, 37 (6), 546.
                                  • highlighted in Chimia, 2012, 66 (6), 442.
                                • 5814 L. Tian, R. Szilluweit, R. Marty, L. Bertschi, M. Zerson, E.-C. Spitzner, R. Magerle, H. Frauenrath, Development of a Robust Supramolecular Method to Prepare Well-Defined Nanofibrils from Conjugated Molecules, Chem. Sci., 2012, 3, 1512-1521.
                                • 5715 E.-C. Spitzner, C. Riesch, R. Szilluweit, L. Tian, H. Frauenrath, R. Magerle, Multi-Set Point Intermittent Contact (MUSIC) Mode Atomic Force Microscopy of Oligothiophene Fibrils, ACS Macro Lett., 2012, 1, 380-383.
                                  • 5616 S. Schrettl, H. Frauenrath, Elements for a Rational Polymer Approach towards Carbon Nanostructures, Angew. Chem. Int. Ed., 2012, 51, 6569-6571.
                                    • 5517 T. N. Hoheisel, S. Schrettl, R. Szilluweit, H. Frauenrath, Nanostructured Carbonaceous Materials from Molecular Precursors, Angew. Chem. Int. Ed., 2010, 49, 6496-6516.
                                      • 5418 J. Gebers, D. Rolland, H. Frauenrath, Coordination-Driven Self-Assembly of PEO-Functionalized Perylene Bisimides - Supramolecular Diversity from a Limited Set of Molecular Building Blocks, Angew. Chem. Int. Ed., 2009, 48, 4480-4483.
                                        • 5322 R. Xu, W. B. Schweizer, H. Frauenrath, Perfluorophenyl-Phenyl Interactions in the Crystallization and Topochemical Polymerization of Triacetylene Monomers, Chem. Eur. J., 2009, 15, 9105-9116.
                                          • 5223 T. N. Hoheisel, H. Frauenrath, Glycosylated Oligo(ethynylene)s via a Pd/Zn-Mediated Cross-Coupling Reaction, Chimia, 2009, 63, 208-210.
                                            • 5124 E. Jahnke, J. Weiss, S. Neuhaus, T. N. Hoheisel, H. Frauenrath, Synthesis of Diacetylene-Containing Peptide Building Blocks and Amphiphiles, their Self-Assembly and Topochemical Polymerization in Organic Solvents, Chem. Eur. J., 2009, 15, 388-404.
                                              • 5025 J. Yuan, H. Frauenrath, Synthesis and 13C NMR Spectroscopy of Model Compounds for the Microstructure Analysis of Poly(Vinyl Glycoside)s, Eur. J. Org. Chem., 2009, 43-52.
                                                • 4926 T. N. Hoheisel, H. Frauenrath, A Convenient Negishi Protocol for the Synthesis of Glycosylated Oligo(ethynylene)s, Org. Lett., 2008, 10, 4525-4528.
                                                  • 4827 R. Xu, W. B. Schweizer, H. Frauenrath, Soluble Poly(diacetylene)s Using the Perfluorophenyl-Phenyl Motif as a Supramolecular Synthon, J. Am. Chem. Soc., 2008, 130, 11437-11445.
                                                    • 4728 J. Weiss, E. Jahnke, N. Severin, J. P. Rabe, H. Frauenrath, Consecutive Conformational Transitions and Deaggregation of Multiple-Helical Poly(diacetylene)s, Nano Lett., 2008, 8, 1660-1666.
                                                      • highlighted in ACS Noteworthy Chemistry, 2008, , .
                                                    • 4629 H. Frauenrath, E. Jahnke, A General Concept for The Preparation of Hierarchically Structured π-Conjugated Polymers, Chem. Eur. J., 2008, 14, 2942-2955.
                                                      • 4530 A. Schmidt, H. Frauenrath, Trendbericht Makromolekulare Chemie 2007, Nachr. Chem., 2008, 56, 315-324.
                                                        • 4431 J. Weiss, E. Jahnke, H. Frauenrath, CD Spectroscopy of Multiple-Helical, Oligopeptide-Substituted Poly(diacetylene)s in Solution, Macromol. Rapid Commun., 2008, 29, 330-339.
                                                          • 4332 E. Jahnke, N.Severin, P. Kreutzkamp, J. P. Rabe, H. Frauenrath, Molecular Level Control over Hierarchical Structure Formation and Polymerization of Oligopeptide-Polymer Conjugates, Adv. Mater., 2008, 20, 409-414.
                                                            • highlighted in Nachr. Chem., 2008, 56, 404.
                                                          • 4234 E. Jahnke, A.-S. Millerioux, N. Severin, J. P. Rabe, H. Frauenrath, Functional, hierarchically Structured Poly(Diacetylene)s via Supramolecular Self-Assembly, Macromol. Biosci., 2007, 7, 136-143.
                                                            • 4135 J. Yuan, K. Lindner, H. Frauenrath, 1-O-Vinyl Glycosides via Tebbe Olefination, Their Use as Chiral Auxiliaries and Monomers, J. Org. Chem., 2006, 71, 5457-5467.
                                                              • 4036 R. Xu, V. Gramlich, H. Frauenrath, Alternating Diacetylene Copolymer Utilizing Perfluorophenyl-Phenyl Interactions, J. Am. Chem. Soc., 2006, 128, 5541-5547.
                                                                • 3937 E. Jahnke, I. Lieberwirth, N. Severin, J. P. Rabe, H. Frauenrath, Topochemical Polymerization in Supramolecular Polymers of Oligopeptide-Functionalized Diacetylenes, Angew. Chem. Int. Ed., 2006, 45, 5383-5386.
                                                                  • 3842 H. Frauenrath, Dendronized Polymers - Building a New Bridge From Molecules To Nanoscopic Objects, Prog. Polym. Sci., 2005, 30, 325-384.
                                                                    • 3743 H. Frauenrath, H. Keul, H. Höcker, Stereospecific Polymerization of Methyl Methacrylate with Single-Component Zirconocene Complexes: Control of Stereospecificity via Catalyst Symmetry, Macromolecules, 2001, 34, 14-19.
                                                                      • 3644 H. Frauenrath, H. Keul, H. Höcker, Deviation from Single-Site Behavior in Zirconocene/MAO Catalyst Systems, 1. Influence of Monomer, Catalyst, and Cocatalyst Concentration, Macromol. Chem. Phys., 2001, 202, 3543-3550.
                                                                        • 3545 H. Frauenrath, H. Keul, H. Höcker, Deviation from Single-Site Behavior in Zirconocene/MAO Catalyst Systems, 2. Influence of Polymerization Temperature, Macromol. Chem. Phys., 2001, 202, 3551-3559.
                                                                          • 3446 H. Frauenrath, S. Balk, H. Keul, H. Höcker, First Synthesis of an AB Block Copolymer with Polyethylene and Poly(methyl methacrylate) Blocks using a Zirconocene Catalyst, Macromol. Rapid Commun., 2001, 22, 1147-1151.
                                                                            • 3350 H. Frauenrath, H. Keul, H. Höcker, Polymerization of 1-Hexene Catalyzed by Bis(cyclopentadienyl)zirconium Dichloride/Methylaluminoxane; Effect of Temperature on the Molecular Weight and the Microstructure of Poly(1-hexene), Macromol. Rapid Commun., 1998, 19, 391-395.

                                                                              Books and Book Chapters

                                                                              • 32128 B. Schulte, S. Schrettl, H. Frauenrath, Synthesis and Use of Reactive Molecular Precursors for the Preparation of Carbon Nanomaterials in Chemistry of Carbon Nanostructures, De Gruyter, Berlin/Boston, 2017, 289–314,.
                                                                                • 3133 E. Jahnke, H. Frauenrath, Strategies toward Hierarchically Structured Optoelectronically Active Polymers in Tomorrows Chemistry Today - Concepts in Nanoscience, Organic Materials, and Environmental Chemistry, B. Pignataro (ed.), Wiley-VCH, 2008, 73-100.
                                                                                  • 3047 H. Frauenrath, H. Keul, H. Höcker, Single Component Zirconocene Catalysts for the Stereospecific Polymerization of MMA in Organometallic Catalysts and Olefin Polymerization, Springer Verlag, Berlin, 2001, 97-108.
                                                                                    • 2949 H. Frauenrath, H. Keul, H. Höcker, Coexistence of Two Active Species in the Polymerization of 1-Hexene Catalyzed with Zirconocene/MAO Catalysts in Metalorganic Catalysts for Synthesis and Polymerization, Springer-Verlag, Berlin, 1999, 283-293.

                                                                                      Other Publications

                                                                                      • 2867 S. Schrettl, H. Frauenrath, Low-temperature Preparation of Functional Carbon Nanocapsules via Self-Assembly and Carbonization of Hexayne Amphiphiles, Chimia, 2013, 67, 429-429.
                                                                                        • 2768 T. N. Hoheisel, R. Szilluveit, S. Schrettl, H. Frauenrath, Carbon-Rich Nanostructures from Molecular Precursors, MRS Proceedings, 2011, .
                                                                                          • 2669 H. Frauenrath, R. Marty, Nanostructured organic materials from Molecular Precursors. Production of Synthetic Polymers with Hierarchical Structures, GIT Laborfachzeitschrift, 2011, 55, 244–246.
                                                                                            • 2570 H. Frauenrath, Hierarchically Structured Conjugated Polymers, Mater. Res. Soc. Symp. Proc., 2010, 1236, 1206-1209.
                                                                                              • 2471 H. Frauenrath, L. Tian, Nanostructures from Oligopeptide-Polymer Conjugates, Polym. Prepr., 2009, 50, 533-534.
                                                                                                • 2372 H. Frauenrath, L. Tian, E. Jahnke, Multiple-Helical Conjugated Polymers, Polym. Prepr., 2009, 50, 390-391.
                                                                                                  • 2273 H. Frauenrath, L. Tian, Nanostructures from Oligopeptide-Polymer Conjugates, Am. Chem. Soc., 2009, 238, POLY-547.
                                                                                                    • 2174 H. Frauenrath, L. Tian, E. Jahnke, Multiple-Helical Conjugated Polymers, Am. Chem. Soc., 2009, 238, POLY-461.
                                                                                                      • 2075 H. Frauenrath, J. Yuan, Preparation and Microstructure of Poly(vinyl glycoside)s and Their Copolymers, Am. Chem. Soc., 2009, 238, POLY-189.
                                                                                                        • 1976 H. Frauenrath, T. N. Hoheisel, S. Schrettl, R. Marty, Carbon-Rich Nanostructures from Molecular Precursors, Am. Chem. Soc., 2009, 238, ORGN-430.
                                                                                                          • 1877 H. Frauenrath, R. Xu, Perfluorophenyl-Phenyl Interactions as Supramolecular Synthon for Crystal Engineering and Topochemical Polymerization, Am. Chem. Soc., 2009, 238, ORGN-345.
                                                                                                            • 1778 H. Frauenrath, J. Gebers, K. P. Pernstich, D. M. DeLongchamp, L. J. Richter, D. A. Fischer, Hydrogen-Bonded Oligothiophenes Processable from Polar Solvents, Am. Chem. Soc., 2009, 238, ORGN-150.
                                                                                                              • 1679 H. Frauenrath, J. Gebers, T. N. Hoheisel, L. Tian, Supramolecular Approaches toward Organic Electronic and Carbonaceous Materials, Am. Chem. Soc., 2009, 238, ORGN-097.
                                                                                                                • 1584 H. Frauenrath, J. Yuan, Preparation and Microstructure of Poly(vinyl glycoside)s and Their Copolymers, Polym. Prepr., 2009, 50, 232-233.
                                                                                                                  • 1480 A. Schmidt, H. Frauenrath, R. Weberskirch, F. Schniedens, H. Heckroth, Macromolecular Chemistry 2007, Nachr. Chem., 2008, 56, 315-324.
                                                                                                                    • 1381 H. Frauenrath, E. Jahnke, A.-S. Millerioux, I. Lieberwirth, N. Severin, J. P. Rabe, Toward Functional, Hierarchically Structured, Optoelectronic Materials, Polym. Prepr., 2006, 47, 459-46.
                                                                                                                      • 1282 H. Frauenrath, E. Jahnke, A.-S. Millerioux, I. Lieberwirth, N. Severin, J. P. Rabe,, Topochemical Polymerizations in Supramolecular Polymers of Oligopeptide Substituted Diacetylenes, Polym. Prepr., 2006, 47, 457-458.
                                                                                                                        • 1183 H. Frauenrath, R. Xu, V. Gramlich, Polymerization of Di- and Triacetylenes Utilizing Perfluorophenyl/Phenyl Interactions, Polym. Prepr., 2006, 47, 596-597.
                                                                                                                          • 1085 H. Frauenrath, J. Yuan, K. Lindner, New Glycopolymers via Synthesis and Polymerization of 1-O-Vinyl Glycosides, Polym. Prepr., 47, 566-567.
                                                                                                                            • 986 H. Frauenrath, J. Yuan, Preparation and Microstructure of Poly(vinyl glycoside)s and Their Copolymers, Abstr. Pap. Am. Chem. Soc., 2006, 232, POLY-189.
                                                                                                                              • 887 H. Frauenrath, R. Xu, V. Gramlich,, Polymerization of Di- and Triacetylenes Utilizing Perfluorophenyl/Phenyl Interactions, Am. Chem. Soc., 2006, 232, POLY-185.
                                                                                                                                • 788 H. Frauenrath, J. Yuan, K. Lindner, New Glycopolymers via Synthesis and Polymerization of 1-O-Vinyl Glycosides, Am. Chem. Soc., 2006, 232, POLY-181.
                                                                                                                                  • 689 H. Frauenrath, E. Jahnke, A.-S. Millerioux, I. Lieberwirth, N. Severin, J. P. Rabe,, Topochemical Polymerizations in Supramolecular Polymers of Oligopeptide Substituted Diacetylenes, Am. Chem. Soc., 2006, 232, POLY-132.
                                                                                                                                    • 590 H. Frauenrath, E. Jahnke, A.–S. Millerioux, I. Lieberwirth, N. Severin, J. P. Rabe,, Toward Functional, Hierarchically Structured, Optoelectronic Materials, Abstr. Pap. Am. Chem. Soc., 2006, 232, POLY-037.

                                                                                                                                      Patents

                                                                                                                                      • 45 E. Croisier, H. Frauenrath, S. Liang, V. Michaud, Blends of Oligopeptide-Terminal Polyisobutylene or Polystyrene, , Switzerland (assignee), Patent WO2014080043A1, 2014 .
                                                                                                                                        • 364 H. Frauenrath, R. Ferrini, L. Zuppiroli, S. Suarez, R. N. Marty, J. G. McMullen, M. Schaer, Color Conversion Films Comprising Polymer-Substituted Organic Fluorescent Dyes, , Switzerland (assignee), Patent US20120301724A1, 2012 .
                                                                                                                                          • 266 H. Frauenrath, R. Ferrini, L. Zuppiroli, S. Suarez, R. Marty, J. McMullen, M. Schaer, Color Conversion Films Comprising Polymer-Substituted Organic Fluorescent Dyes, , Switzerland (assignee), Patent WO2012160521A1, 2012 .
                                                                                                                                            • 165 H. M. Koenig, A. Lange, H. Frauenrath, J. Gebers, E. Croisier, L. Su, K. Feher, R. Marty, Preparation of Block Copolymers as Thermoplastic Elastomers made of Polyisobutene Blocks and Oligoamide Blocks, , Germany (assignee), , Patent WO2011045309A1, 2011 .
                                                                                                                                              ++ ??autogenerate those PDFs at the top?
                                                                                                                                              ++ Do we want to keep them at all?
                                                                                                                                              
                                                                                                                                              ++ ??Move CV as pdf to the main Holger page?
                                                                                                                                              

                                                                                                                                              Contact Information

                                                                                                                                              Laboratory of Macromolecular and Organic Materials

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                                                                                                                                              EPFL–STI–IMX–LMOM
                                                                                                                                              MXG 037
                                                                                                                                              Station 12
                                                                                                                                              1015 Lausanne
                                                                                                                                              Switzerland
                                                                                                                                              Phone
                                                                                                                                              +41 21 693 7395
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                                                                                                                                              News & Highlights

                                                                                                                                              • - Reuben Yeo joined the group as a postdoc.
                                                                                                                                              • - Alexis Claveau joined the group as a PhD Student.
                                                                                                                                              • - Nicolas Candau joined the group as a postdoc.